ChemicalBook > CAS DataBase List > (s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE
(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE
Reaction- Product Name
- (s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE
- CAS No.
- 447440-43-9
- Chemical Name
- (s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE
- Synonyms
- 1-Oxa-3-aza-2-silacyclopentane,2-chloro-3,4-dimethyl-5-pheny...;(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE;(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazasilolidine;(4S,5S)-2-chloro-3,4-dimethyl-5-phenyl-2-prop-2-enyl-1,3,2-oxazasilolidine;(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane ;1-Oxa-3-aza-2-silacyclopentane, 2-chloro-3,4-dimethyl-5-phenyl-2-(2-propen-1-yl)-, (4S,5S)-
- CBNumber
- CB72134999
- Molecular Formula
- C13H18ClNOSi
- Formula Weight
- 267.83
- MOL File
- 447440-43-9.mol
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(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Property
- Density
- 1.095 g/mL at 25 °C
- refractive index
- n20/D1.517
- Flash point:
- 38℃
- pka
- 4.43±0.60(Predicted)
- Specific Gravity
- 1.01
- optical activity
- [α]20/D 72.5°, c = 0.6 in ethanol (200 proof)
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- Sensitive
- moisture sensitive, store cold
- Boiling point:
- 120°C/5 mmHg
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Safety
- Hazard Codes
- F,Xi
- Risk Statements
- 10-15-36/37/38
- Safety Statements
- 26
- RIDADR
- UN 3132 / PGII
- WGK Germany
- 3
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H226Flammable liquid and vapour
H261In contact with water releases flammable gas
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P231+P232Handle under inert gas. Protect from moisture.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P422Store contents under …
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N-Bromosuccinimide Price
Strem Chemicals
- Product number
- 14-1815
- Product name
- (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)
- Packaging
- 1g
- Price
- $99
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 14-1815
- Product name
- (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)
- Packaging
- 5g
- Price
- $395
- Updated
- 2024/03/01
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(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Chemical Properties,Usage,Production
Reaction
Versatile reagent for the enantioselective allylation of aldehydes and hydrazones.
Uses
Leighton′s Strained Silacycles: Powerful Enantioselective Allylation Reagents
- Practical, enantioselective allylation of acylhydrazones
- Enantioselective allylation of ketimines: synthesis of tertiary carbinamines
General Description
This product is a mixture of diastereomers.
(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Preparation Products And Raw materials
Raw materials
Preparation Products
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(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Suppliers
- Tel
- +1-833-552-7181
- sales@aladdinsci.com
- Country
- United States
- ProdList
- 52927
- Advantage
- 58
447440-43-9, (s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINERelated Search:
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(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE